With windows XP you have 2 firewalls (XP & macafee). Just double-check you have set them up correctly to allow both LW & Java full access:
http://www.limewire.com/english/content/firewalls.shtml
ALso can you tell us these things:
* Connection type,
* Modem & router brand name & model numbers,
* Where are you trying to connect from (home, school, work, etc.)?
High speed modems often also have their own internal firewall or NAT.