Simply open a new email, click attatch and browse your computer for the file. There is a limit on the file size depending on your subscription type, so you will have to check that out. More in the help page.

Larger files can be uploaded to yousendit.com or sendthisfile.com with your browser who will advise the recipient of the file by email and they download it with their browser

You can also send them using a chat client like aim or msn

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