when people suddenly can't connect after upgrading to Pro, deleting the preferences folder is often the fix.

Delete LW's preferences folder when LW's properly closed. See point 3 here & also point 2 if you've used older versions of LW in the past (there could be a folder in either location).
Fixes for LimeWire
This will change all of your settings within options, you'll have to go back through afterwards & reset things. If you're not sure of your settings, go through LW's tools > options & write them all down, so that you can reset things later.

Your Java version's quite old. You can either update to the latest version here (I have this one & LW's working fine): Java SE Downloads
or try this older version, which has worked well for lots of people: Archive: Download Java 2 Platform Standard Edition (J2SE) 5.0 Update 11
Whichever Java version you use, download the JRE offline installer & remove any other Java versions before installing another one.

Rather than running without a firewall, make sure that the XP firewall's allowing LW.
User Cant Connect - LimeWire

What is the model of your Belkin?