Hi Dave,
I thought as much when I saw your 1st post of this thread -- your problem is your ISP TISCALI - they are known to throttle P2P see this link for ISP's known to Block P2p or specifically Limewire.

Have a look at this link I have found a solution to getting Limewire to work with Tiscali

Are you using the paid version of AVG -- if so good this includes a firewall -- if not you have no firewall -- if you have a firewall please enable it.

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Limewire links: (If LW 5 will not connect) (If LW 4 will not connect)(system details) (LW Clean Reinstallation Instructions) (setting up your firewall to accept LW)

LW links are changed at times to match the current problems.